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Why glycol?
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Curt Palme
CRT Tech


Joined: 08 Mar 2006
Posts: 24396
Location: Langley, BC

TV/Projector: All of them!

Posted: Fri Oct 19, 2007 2:49 pm    Post subject: Why glycol?

OK, stupid question time. What properties does glycol have that water or mineral oils (or Koolaid!) don't?

What would happen if you used something like baby oil in place of the glycol?

Just something that's been bugging me for years, and today someone emailed me the same question, so I thought I'd post.
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nuttall_chris



Joined: 08 Mar 2006
Posts: 832
Location: Ottawa, Ontario, Canada

Posted: Fri Oct 19, 2007 2:58 pm    Post subject:

Water expands when frozen (glycol doesn't). Most of the projectors are rated for storage temperatures below the freezing point of water. Expanding frozen water would break the tube face on AC sets and possible rupture the bellows on LC sets.

Also on LC sets the lenses/C-elements have been designed to work with glycol which has a higher index of refraction than water.

As for other substances....mineral oils, baby oil, Koolaid...don't know.

Chris
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Z-Photo



Joined: 07 Mar 2006
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Location: Huntsville - Alabama

Posted: Fri Oct 19, 2007 4:02 pm    Post subject:

glycol is non-flammable-

Baby oil - not so much.

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jask



Joined: 17 Mar 2006
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Location: kamloops BC

Posted: Fri Oct 19, 2007 7:25 pm    Post subject:

I think it is actually the optical refraction that would be the most correct answer Very Happy

edit: the purpose is to as closely match the index of refraction in all the materials of the optical path..
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drice1234



Joined: 07 Oct 2006
Posts: 1309
Location: Allen, Texas

Posted: Fri Oct 19, 2007 7:52 pm    Post subject:

Quote:
glycol is non-flammable-

Baby oil - not so much.


I would very much like to hear the story on how this was discovered Shocked
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kal
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Joined: 06 Mar 2006
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Posted: Fri Oct 19, 2007 8:10 pm    Post subject:

Having spent the last 2-3 weeks trying different fluids for cooling my beer taps and lines and doing a lot of research on it, it also has to do with heat transfer coefficients and efficiency. Glycol's really good and consistent in this way - you don't get hot/cold spots (and it also has a much lower freezer point/much high boiling point).

Water just doesn't work that well for cooling. One of the reasons why you don't have water in your car radiator either.

Kal

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jask



Joined: 17 Mar 2006
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Posted: Fri Oct 19, 2007 8:15 pm    Post subject:

this is a list of the indices of refraction for a few materials (no cool-aid, but you could just keep adding sugar till you hit the target gravity..)
acrylic glass 1.49
crown glass 1.52 (optical glass)


water 1.33 (@20C)
alcohol 1.36 grain
alcohol 1.32 wood
glycerine 1.47
turpentine 1.47
veg oil 1.47
lab oil 1.515 microscope oil

Glycol has the added bonus of being a very good conductor of heat,
if the tube face ever cracked a non-flamable fluid would make the choice of glycol over oil much easier!! I found a link to a patent that used siloxane polymers (silicone liquid) with a matched index for CRT projection lens groups...
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ecrabb
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Joined: 13 Mar 2006
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Posted: Fri Oct 19, 2007 8:16 pm    Post subject:

I think it's all of the above.

Compared to water, ethylene glycol/glycerol has:
- lower surface tension (better interface between materials, fewer bubbles)
- a lower freezing point
- a higher boiling point
- an index of refraction closer to typical lens materials
- better thermal conductivity (like Kal mentioned - this and the freeze/boil points are why ethylene glycol is a good automotive coolant)

If you do some googling, you can find some patents from people working on some cool polymer-based coolants with similar properties to glycol, but non-corrosive and non-conductive. Wouldn't that have been cool (sorry, bad pun)? Too bad they were working on that stuff right before CRT's started their precipitous popularity decline. Stupid digitals.

SC
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bengalfan



Joined: 17 Mar 2006
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Location: Moline, Ohio

Posted: Fri Oct 19, 2007 8:50 pm    Post subject:

Ethylene glycol (a type of alcohol) has a very good coefficient of exansion (0.00099), excellant clarity, and a very low refrative index (1.406) . It also has a high flash point of ~ 120°+ F and bp of 275° C. this is important, means it can absorb alot of heat w/o expansion (or at least minimal).
It appears that Barco also used some glycerol blended into the et-glycol, probably as a humectant.

Mineral oils (baby oils) are alkanes, part of the early cracking process of petroleums. As such, the flash point would be in the dangerous area (fire and projector, bad), plus with all the impurities the clarity would not be good, and the coef of expansion is not very good at all. It does expand with heat, but I don't know at what level.

Water - gets hot quickly and POP, there goes that nice lens.

So save the oil to slather up your honey and keep it away from the projector. Very Happy

Van

(finally something I can write about!)

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stefuel



Joined: 07 Mar 2006
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Location: Green Harbor MA USA

Posted: Fri Oct 19, 2007 9:36 pm    Post subject:

God you guys crack me up with all your slide-rules, flash point and refractive index's. I've tried straight medical grade distilled water and it works just fine. In fact the sharpest image you'll ever get out of a LC. The only thing I can't say is how long before corrosion occurs.
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lucht
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Posted: Fri Oct 19, 2007 10:16 pm    Post subject:

bengalfan wrote:

It appears that Barco also used some glycerol blended into the et-glycol, probably as a humectant.


Glycerine is hunectant (E1520), but a mixer with glycerine has a higher refractio index which bring it closer to these from your c-element. And you reduce the reflection from a normale air/glas from 4% to less 0,5% which is also possible with a good coating

From US patent 6268458

To date, ethylene glycol, mixtures of ethylene glycol and glycerol, and mixtures of ethylene glycol and water have been employed extensively as coupling fluids in projection TVs. The preferred fluid in recent years has been ethylene glycol/glycerol mixtures due to the relatively low volatility of the constituent components. As a result, the loss of coupling fluid through the last lens element of the projection lens system has been minimized. Also, the refractive index of an ethylene glycol/glycerol mixture is higher than pure ethylene glycol or a mixture of ethylene glycol and water. In addition, ethylene glycol/glycerol mixtures exhibit reasonable environmental friendliness, the ability to operate near 90° C., low cost, good compatibility with molded optics, good thermal conductivity, and good optical clarity.

A preferred composition for coupling fluids of this type has been 80% ethylene glycol and 20% glycerol. Further addition of glycerol would cause the projected image to squirm, due to natural convection associated with thermal gradients in a viscous fluid.
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Fujifrontier



Joined: 20 Oct 2007
Posts: 354
Location: San Antonio, Texas

Posted: Sat Oct 20, 2007 2:34 am    Post subject:

*ahem*

Good evening, sirs Smile

I was actually the person who asked Curt the question earlier, and he responded lightning-quick, which I appreciate greatly.

The reason I'm asking is because on another forum they were talking about Magnavox RPTVs, whose CRTs like to grow the algae/deposits; and one of the members said you could just refill the CRT chamber with mineral oil. I thought it unlikely... and was wondering what other (safe) substitutes could be used, 'cos I admit I had a bit of sticker shock from the price of pure glycol.

How hot do the tubes normally run? How many containers of glycol would I need; the $46 isn't for a set of 3 bottles, is it?
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Tom.W



Joined: 09 Mar 2006
Posts: 6635


Posted: Sat Oct 20, 2007 3:37 am    Post subject:

You might want to read this thread also..

https://www.curtpalme.com/forum_archived/viewtopic.php@t=6894.html
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mr_ro_co



Joined: 08 May 2006
Posts: 1643
Location: Santa Fe NM

Posted: Sat Oct 20, 2007 1:43 pm    Post subject:

Isn't it propylene glycol (usually mixed with some water and glycerin), not ethylene glycol, that's used in crt projectors?

I had to take apart the entire chassis on my 9500 Ultra to clean up a major glycol leak that occurred in shipping. The stuff I was cleaning up looked and smelled just like the stuff that runs in HVAC chilled water and condenser water systems, which is typically propylene glycol. My understanding was ethylene glycol is used in applications that involve much higher temperatures (such as a car radiator).

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Z-Photo



Joined: 07 Mar 2006
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Location: Huntsville - Alabama

Posted: Sat Oct 20, 2007 1:48 pm    Post subject:

stefuel wrote:
God you guys crack me up with all your slide-rules, flash point and refractive index's. I've tried straight medical grade distilled water and it works just fine. In fact the sharpest image you'll ever get out of a LC. The only thing I can't say is how long before corrosion occurs.


How would you notice if an Ampro had corrosion?

Reminds me of a needle and haystack

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Tom.W



Joined: 09 Mar 2006
Posts: 6635


Posted: Sat Oct 20, 2007 2:27 pm    Post subject:

Just talked with Mat electronics and they have 500 16oz bottles of Teck Spray CRT coolent coming in next week. It was on back order. Still $5.50 a bottle if ordering 10 or more.

http://www.matelectronics.com/acatalog/Mat_Electronics_Chemicals___Tech_Spray_59.html

Here's the MSDS sheet for Teck Spray. 25 % glycerin and 75% ethylene glycol

http://www.mcminone.com/content/ProductData/MSDS/20-4275.pdf
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Tom.W



Joined: 09 Mar 2006
Posts: 6635


Posted: Tue Oct 30, 2007 12:24 am    Post subject:

Just recieved the back ordered Tech spray glycol/glycerin mix today from Mat electronics Thumbs Up Thumbs Up Thumbs Up
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jask



Joined: 17 Mar 2006
Posts: 10187
Location: kamloops BC

Posted: Tue Oct 30, 2007 5:23 am    Post subject:

Tom.W wrote:
Just recieved the back ordered Tech spray glycol/glycerin mix today from Mat electronics Thumbs Up Thumbs Up Thumbs Up


How did they ship it?
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Tom.W



Joined: 09 Mar 2006
Posts: 6635


Posted: Tue Oct 30, 2007 11:59 am    Post subject:

15 pounds UPS ground $15.44. Got 10 16oz bottles.
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ILOVEMYTHEATRE



Joined: 23 Jan 2007
Posts: 6
Location: NHILL, VIC AUSTRALIA

Posted: Wed Oct 31, 2007 10:34 am    Post subject: glcol vs baby oil

Well ,read all the tech stuff posted and it all sounds like I should not have had used baby oil , but its been in my sony D50 for the past 6 years with no ill effects .The projectors been runnning with ambient room temperature around "35 degrees C " (or around 95 degrees F for our US friends) besides it smells nice too Tried it in my frie Very Happy nds 1252 but the rubber groment swelled up
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